
Recent Publications
These papers describe for the first time a method for multiscale correlation of spectroscopic probes. It is shown that it is possible to relate surface enhanced resonance Raman scattering (SERRS) from nanoparticles with measurements of the surface plasmon resonance using EELS in the electron microscope. This major achievement allows the spatial distribution of the plasmon on individual and aggregated nanoparticles to be studied with the knowledge of which particles exhibit a SERRS effect and which do not. It is demonstrated that the surface plasmon varies between particles and within particles. These publications open up the possibility of addressing two key areas in nanoparticle plasmonic research. Firstly, we can provide experimental evidence to support or challenge theories on the origin of the surface enhancement effect. Fundamental understanding of the effect is essential to realise the potential of SERRS from nanoparticles as a detection technique to meet the ever increasing demands for more sensitive and more selective analysis methods for targets such as bioanalytes including DNA, antibodies and enzymes and for illicit drugs and explosives. Secondly, we can investigate the spatial variation of surface plasmons in particles with unprecedented spatial and energy resolution. This information will improve understanding of the fundamental physics and aid the development of localised models for surface plasmon behaviour.
This publication illustrates the power of electron energy-loss spectroscopy as a characterization technique. When carried out in a modern nano-analytical electron microscope it is shown that this method can provide insights into the chemical and bonding environments at interfaces in thin film devices. Such information is critical for the continued development of such structures for device applications.
This paper describes the factors that must be considered if one is to produce high quality PCs by a self-assembly approach. The results of our investigations into these parameters are described and protocol for the production of low defect density structures. The importance of this extends far beyond photonics as it provides a basis for the development of three-dimensionally ordered macroporous solids in the form of robust thin films for potential applications in areas such as fuel cells, catalysis, sensors and other multifunctional devices. We are already implementing our knowledge and expertise to produce ferroelectric, piezoelectric and magnetic thin films with highly ordered porosity.
Biography
Research:
Image 1: Image of InAs quantum dots recorded using the FEI Titan 80-300 (S)TEM
Image 2: SEM image of a cross-section from a thin film opal template for the formation of multifunctional three-dimensionally ordered macroporous solids.